Further to the talk on XNA earlier this week, some folks have been in touch for any other XNA references that I might know of. Here are a couple.
You can find a complete course which teaches programming using XNA at Microsoft Faculty Connection here. There are slides, labs and all kinds of good bits and bobs that you an asset strip and use as the basis of your teaching.
My Microsoft Press XNA 3.0 book (not the most recent, but still good for getting started) can be found as a free download from here.
All of the stuff will work on MonoGame too.